Nanoscale graphene oxide sheets as highly efficient carbocatalysts in green oxidation of benzylic alcohols and aromatic aldehydes
نویسندگان
چکیده
منابع مشابه
Performance comparison of graphene and graphene oxide-supported palladium nanoparticles as a highly efficient catalyst in oxygen reduction
In this work, the performance of graphene nanosheets (GNs) and graphene oxide (GO) nanosheets, as a support for palladium nanoparticles (PdNPs) toward oxygen reduction reaction (ORR), was studied. The graphene nanosheets were functionalized by a new and simple method. The PdNPs were synthesized on a glassy carbon electrode (GCE) modified with GNs or GO via a potentiostatic method; without using...
متن کاملHighly Confined Phases of Graphene Oxide Sheets
The graphene oxide (GO) is widely used as a graphene precursor. It has been recently evidenced that this object can form different lyotropic liquid crystals phases observed in highly anisotropic colloids. The confinement of GO sheets, a two-dimensional (2D) crystal is herein aim of study. The binary GO water is studied to describe the liquid crystallinity of concentrated dispersions, characteri...
متن کاملOxidation of allylic and benzylic alcohols to aldehydes and carboxylic acids.
An oxidation of allylic and benzylic alcohols to the corresponding carboxylic acids is effected by merging a Cu-catalyzed oxidation using O2 as a terminal oxidant with a subsequent chlorite oxidation (Lindgren oxidation). The protocol was optimized to obtain pure products without chromatography or crystallization. Interception at the aldehyde stage allowed for Z/E-isomerization, thus rendering ...
متن کاملCarbocatalysts: graphene oxide and its derivatives.
Graphene oxide (GO) sheets are emerging as a new class of carbocatalysts. Conventionally, researchers exfoliate graphite oxide into submicrometer-sized, water-dispersible flakes to produce these sheets. The presence of oxygen functional groups on the aromatic scaffold of GO allows these sheets to mediate ionic and nonionic interactions with a wide range of molecules. GO shows remarkable catalyt...
متن کاملHighly reduced graphene oxide supported Pt nanocomposites as highly efficient catalysts for methanol oxidation.
The highly reduced graphene oxide using solvated electrons as reductive agents shows low defects and well dispersion that are vital as the support of Pt nanoparticles in direct methanol electro-oxidation. The electrochemical experiments demonstrate that the Pt/RGO composites not only greatly enhance the catalytic activity but also dramatically improve the durability of the catalyst.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chinese Journal of Catalysis
سال: 2017
ISSN: 1872-2067
DOI: 10.1016/s1872-2067(17)62776-1